Bis[(cyanido-κC)bis(1,10-phenanthroline-κ2N,N′)copper(II)] pentakis(cyanido-κC)nitrosoferrate(II) dimethylformamide monosolvate

Bis[(cyanido-κC)bis(1,10-phenanthroline-κ2N,N′)copper(II)] pentakis(cyanido-κC)nitrosoferrate(II) dimethylformamide monosolvate

Blog Article

The title compound, [Cu(CN)(C12H8N2)2]2[Fe(CN)5(NO)]·C3H7NO, is formed of discrete [Cu(phen)2CN]+ cations (phen is 1,10-phenanthroline), nitroprusside [Fe(CN)5(NO)]2− anions and dimethylformamide (DMF) molecules of crystallization.The metal FACE OIL atom has a distorted trigonal–bipyramidal coordination environment, defined by four N atoms of two phen molecules and a C atom of the cyanide group (in the equatorial position).The [Fe(CN)5(NO)]2− anion was found to Toothbrush Charging Cord be disordered about (but not on) a crystallographic twofold rotation axis.Geometries were restrained to ideal values.

The dimethylformamide solvent molecule was found to be disordered about a crystallographic inversion centre.